Asymmetric hydroamination with far fewer chiral species than copper centers achieved by tuning the structure of supramolecular helical catalysts
نویسندگان
چکیده
Mixing a BTA ligand (in black), “sergeant” blue) and an achiral additive orange) affords the amination product in 75% e.e. even though only one for ca. 10 copper centers are present supramolecular helical catalyst.
منابع مشابه
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ژورنال
عنوان ژورنال: Catalysis Science & Technology
سال: 2022
ISSN: ['2044-4761', '2044-4753']
DOI: https://doi.org/10.1039/d1cy02168k